Huckerby, Thomas N. and Brown, Gavin M. and Nieduszynski, Ian A. (1995) <sup>13</sup>C-NMR spectroscopy of keratan sulphates. European Journal of Biochemistry, 231 (3). pp. 779-783.
Full text not available from this repository.Abstract
Skeletal keratan sulphate has been fragmented using the enzyme keratanase II, and the complete <sup>13</sup>C chemical shift data are reported for the four tetrasaccharides which derived from the repeat region. They have the structures: Galβ(1–4)GlcNAc(6S)β(1–3)Galβ(1–4)GlcNAc(6S)-ol, Gal(6S)β(1–4)GlcNAc(6S)β(1–3)Gal(1–4)GlcNAc(6S)-ol, Galβ(1–4)GlcNAc(6S)β(1–3)Gal(6S)β(1–4)GlcNAc(6S)-ol, and Gal(6S)β(1–4)GlcNAc(6S)(1–3)Gal(6S)β(1–4)GlcNAc(6S)-ol, where GlcNAc(6S)-ol represents N-acetyl-glucosaminitol-6-O-sulphate. The value of these data for microstructural analysis of undegraded keratan sulphate samples using <sup>13</sup>C-NMR spectroscopy is discussed with respect to galactose sulphation levels and the block sulphation structure.
| Item Type: | Article |
|---|---|
| Journal or Publication Title: | European Journal of Biochemistry |
| Subjects: | G Geography. Anthropology. Recreation > GE Environmental Sciences |
| Departments: | Faculty of Science and Technology > Lancaster Environment Centre Faculty of Health and Medicine > Biomedical & Life Sciences VC's Office |
| ID Code: | 22282 |
| Deposited By: | ep_ss_importer |
| Deposited On: | 06 Feb 2009 15:12 |
| Refereed?: | No |
| Published?: | Published |
| Last Modified: | 26 Jul 2012 15:58 |
| Identification Number: | |
| URI: | http://eprints.lancs.ac.uk/id/eprint/22282 |
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