Akyüz, Sevim and Bakiler, Meriç and Davies, J. Eric D. (1996) A vibrational spectroscopic study of transition metal tetracyanonickelate complexes of 2-chloropyridine and 2-bromopyridine. Journal of Coordination Chemistry, 37 (1-4). pp. 1-6. ISSN 1029-0389
Full text not available from this repository.Abstract
The FT-IR and Raman spectra of eight new complexes of formula ML2Ni(CN)4 (where M = Mn, Fe, Co, Ni, Cu or Cd and L = 2-chloropyridine; M = Ni or Cd and L = 2-bromopyridine) are reported. The spectroscopic results indicate that the complexes have structures consisting of corrugated polymeric layers of [M-Ni(CN)4]∞ with 2-substituted pyridine molecules bound directly to the metal (M). For a given ligand (2-Clpy or 2-Brpy) the effects of metal-ligand bond formation on the ligand modes are examined. Metal-ligand bond strengths of the halo-derivatives of pyridine (L = 2-Clpy or 2-Brpy), inferred by the effects on frequency shifts of certain ligand modes, have also been compared.
| Item Type: | Article |
|---|---|
| Journal or Publication Title: | Journal of Coordination Chemistry |
| Uncontrolled Keywords: | tetrocyanonickelate ; vibrational spectroscopy ; transition metal |
| Subjects: | G Geography. Anthropology. Recreation > GE Environmental Sciences |
| Departments: | UNSPECIFIED |
| ID Code: | 21980 |
| Deposited By: | ep_ss_importer |
| Deposited On: | 17 Feb 2009 09:11 |
| Refereed?: | Yes |
| Published?: | Published |
| Last Modified: | 26 Jul 2012 15:54 |
| Identification Number: | |
| URI: | http://eprints.lancs.ac.uk/id/eprint/21980 |
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