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A fourier-transform infrared and laster-raman spectroscopic study of 4,4'-bipyridyl transition metal (II) tetracyanonickelate ciathrates.

Akyüz, Sevim and Akyüz, Tanil and Davies, J. Eric D. (1996) A fourier-transform infrared and laster-raman spectroscopic study of 4,4'-bipyridyl transition metal (II) tetracyanonickelate ciathrates. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 26 (1-3). pp. 111-117. ISSN 0923-0750

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Abstract

The FT-IR and Raman spectra are reported of M(4,4-bipyridyl)Ni(CN)4·nG (where M = Mn, Fe, Co, Cu or Zn and G = benzene or aniline;n = 0–2) clathrates. The host structure consists of a three-dimensional rigid lattice formed by infinite polymeric layers of {M-Ni(CN)4} and 4,4-bipyridyl bridges between the metal (M) atoms of the adjacent polymeric layers. Bidentate 4,4-bipyridyl molecules are found to be centrosymmetric in the structure.

Item Type: Article
Journal or Publication Title: Journal of Inclusion Phenomena and Macrocyclic Chemistry
Uncontrolled Keywords: Tetracyanonickelate compounds - benzene clathrate - aniline clathrate - IR and Raman spectra - 4 ; 4-bipyridyl complexes
Subjects: G Geography. Anthropology. Recreation > GE Environmental Sciences
Departments:
ID Code: 21979
Deposited By: ep_ss_importer
Deposited On: 17 Feb 2009 09:15
Refereed?: Yes
Published?: Published
Last Modified: 26 Jul 2012 15:54
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/21979

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