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Clathrate and inclusion compounds : 12 : vibrational and NMR spectroscopic studies of carboxylic acid guests in Dianin's compound.

Davies, J. Eric D. and Tabner, Vivienne A. (1997) Clathrate and inclusion compounds : 12 : vibrational and NMR spectroscopic studies of carboxylic acid guests in Dianin's compound. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 27 (2). pp. 179-190. ISSN 0923-0750

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Abstract

Infrared, Raman and solid state 13C-NMR spectra have been recorded for a range of clathrates of Dianin''s compound containing straight chain aliphatic carboxylic acids (formic - octanoic) as guests. The IR, Raman and NMR spectra can be satisfactorily interpreted in terms of dimer (formic and acetic) and monomer (propionic - octanoic) occupation of the cavities. The clathrates containing straight chain alcohol guests (methanol - octanol) have also been prepared to aid in the interpretation of the NMR data.

Item Type: Article
Journal or Publication Title: Journal of Inclusion Phenomena and Macrocyclic Chemistry
Uncontrolled Keywords: IR spectroscopy - Raman spectroscopy - 13C-MAS NMR spectroscopy - Dianin''s compound - clathrates - carboxylic acids - alcohols
Subjects: G Geography. Anthropology. Recreation > GE Environmental Sciences
Departments: Faculty of Science and Technology > Lancaster Environment Centre
Faculty of Health and Medicine > Biomedical & Life Sciences
Faculty of Arts & Social Sciences
ID Code: 21913
Deposited By: ep_ss_importer
Deposited On: 12 Feb 2009 10:25
Refereed?: Yes
Published?: Published
Last Modified: 26 Jul 2012 15:53
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/21913

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