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FT-IR and FT-Raman spectroscopic investigations of adsorption of 2,2 '-biquinoline by smectite group clay minerals from Anatolia.

Akyüz, Sevim and Akyüz, Tanil and Davies, J. Eric D. (2000) FT-IR and FT-Raman spectroscopic investigations of adsorption of 2,2 '-biquinoline by smectite group clay minerals from Anatolia. Vibrational Spectroscopy, 22 (1-2). pp. 11-17. ISSN 0924-2031

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Abstract

The sorption of 2,2′-biquinoline onto natural and ion-exchanged montmorillonite (Fe-, Co- or Cu-montmorillonite) and saponite from Anatolia have been investigated using FT-IR and FT-Raman Spectrometry. The intercalation of 2,2′-biquinoline within natural and ion-exchanged montmorillonite and saponite has been shown by X-ray diffraction to increase the interlayer spacing. The difference of basal spacing of air-dried clays and biquinoline treated ones shows monolayer arrangement. Raman spectroscopy was particularly useful for investigation of clay-organic interaction. Vibrational spectroscopy indicates that intercalated 2,2′-biquinoline molecules are coordinated to exchangeable cations (directly and indirectly through water bridges) and/or Lewis acid sites or as bidentate ligand.

Item Type: Article
Journal or Publication Title: Vibrational Spectroscopy
Uncontrolled Keywords: FT-IR ; FT-Raman ; Clay ; Montmorillonite ; Saponite ; Intercalation ; Biquinoline
Subjects: G Geography. Anthropology. Recreation > GE Environmental Sciences
Departments: UNSPECIFIED
ID Code: 21593
Deposited By: ep_ss_importer
Deposited On: 22 Jan 2009 11:05
Refereed?: Yes
Published?: Published
Last Modified: 26 Jul 2012 15:49
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/21593

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