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Elucidation of quadrupole parameters by simulation of 10B NMR powder patterns

Berkowitz, J. and McConnell, M.R. and Tholen, K. and Feller, S. and Affatigato, M. and Martin, S.W. and Holland, D. and Smith, M.E. and Kemp, T.F. (2009) Elucidation of quadrupole parameters by simulation of 10B NMR powder patterns. Physics and Chemistry of Glasses: European Journal of Glass Science and Technology Part B, 50 (6). pp. 372-377. ISSN 0031-9090

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Abstract

A method has been developed to analyse static 10B NMR spectra and, using exhaustive simulation procedures, we have obtained values for quadrupole parameters and their distribution. Experimental data for vitreous boron oxide, vitreous and crystalline caesium triborate, vitreous caesium diborate, crystalline potassium diborate, and caesium enneaborate have been fitted to yield information on the multiple sites and their quadrupole parameters. These sites may result from differences in short range order, or intermediate range structure. The asymmetry parameter is particularly sensitive to differences in the environments of three-coordinated borons placed in differing intermediate range order positions.

Item Type: Journal Article
Journal or Publication Title: Physics and Chemistry of Glasses: European Journal of Glass Science and Technology Part B
Subjects: ?? ASYMMETRY PARAMETEREXHAUSTIVE SIMULATIONEXPERIMENTAL DATAINTERMEDIATE RANGE ORDERNMR SPECTRUMPOWDER PATTERNSQUADRUPOLESSHORT RANGE ORDERSVITREOUS BORON OXIDEAMORPHOUS MATERIALSBORONBORON COMPOUNDSCRYSTALLINE MATERIALSNUCLEAR MAGNETIC RESONANCE SPECTROSCOP ??
Departments: VC's Office
ID Code: 130316
Deposited By: ep_importer_pure
Deposited On: 04 Jan 2019 12:00
Refereed?: Yes
Published?: Published
Last Modified: 04 Jan 2019 12:00
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/130316

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