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A study of an azonitrile containing a sizable fluorocarbon group.

Bevington, J. C. and Guyot, B. and Huckerby, T. N. and Hunt, B. J. and Jones, R. (2000) A study of an azonitrile containing a sizable fluorocarbon group. European polymer Journal, 36 (4). pp. 657-661. ISSN 0014-3057

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Abstract

The azonitrile of formula (C8F17·[CH2]2·O·CO·[CH2]2·C(CH3)(CN):N:)2 was used to initiate radical polymerizations of styrene and methyl methacrylate at 60°C. It was shown that transfer to initiator and primary radical termination can be neglected for those systems. Fluorine-containing end-groups in the resulting polymers could be easily detected by 19F-NMR, but there were some uncertainties about quantitative determinations; they may have resulted from the presence of impurities in the initiator.

Item Type: Article
Journal or Publication Title: European polymer Journal
Subjects: Q Science > QH Natural history > QH301 Biology
Departments: Faculty of Science and Technology > Lancaster Environment Centre
Faculty of Science and Technology > Engineering
ID Code: 10820
Deposited By: Mr Richard Ingham
Deposited On: 24 Jul 2008 14:37
Refereed?: Yes
Published?: Published
Last Modified: 18 Sep 2013 15:58
Identification Number:
URI: http://eprints.lancs.ac.uk/id/eprint/10820

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