Bevington, J. C. and Huckerby, T. N. and Hunt, B. J. and Jenkins, A. D. (2001) THE EFFECTS OF ALLYL ETHERS UPON RADICAL POLYMERIZATIONS. Journal of Macromolecular Science, Part A Pure and Applied Chemistry, 38 (7). pp. 627-640. ISSN 1520-5738Full text not available from this repository.
Three allyl ethers, viz. the ethyl, 2-hydroxyethyl and phenyl compounds, have been examined as additives in radical polymerizations of styrene (STY), methyl methacrylate (MMA) and acrylonitrile (ACN) at 60°C using azobisisobutyronitrile as initiator. As retarders and transfer agents, the ethers are considerably more effective with ACN than with the other monomers. Allyl phenyl ether engages in significant copolymerization with ACN and slight copolymerization with MMA; there is negligible incorporation in polySTY.
|Journal or Publication Title:||Journal of Macromolecular Science, Part A Pure and Applied Chemistry|
|Uncontrolled Keywords:||Radical polymerization ; Allyl ethers ; Retardation ; Transfer|
|Subjects:||Q Science > QH Natural history > QH301 Biology|
|Departments:||Faculty of Science and Technology > Lancaster Environment Centre|
Faculty of Science and Technology > Engineering
|Deposited By:||Mr Richard Ingham|
|Deposited On:||24 Jul 2008 09:47|
|Last Modified:||26 Jul 2012 14:53|
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